Method for preparing hydroxylamine hydrochloride by using hydrogen chloride dry gas

The invention relates to a method for preparing hydroxylamine hydrochloride by using hydrogen chloride dry gas. The method utilizes a mixture of a filtrate obtained by crystallization and filtering ofan oxime hydrolysis reaction and a water-rich phase of a distillate to absorb hydrogen chloride dry...

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Bibliographische Detailangaben
Hauptverfasser: LONG BO, LIU TIANYU, DU XINYANG, YANG LILEI, ZHANG WEIDONG
Format: Patent
Sprache:chi ; eng
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Beschreibung
Zusammenfassung:The invention relates to a method for preparing hydroxylamine hydrochloride by using hydrogen chloride dry gas. The method utilizes a mixture of a filtrate obtained by crystallization and filtering ofan oxime hydrolysis reaction and a water-rich phase of a distillate to absorb hydrogen chloride dry gas, and the obtained absorption liquid and ketoxime are added to a reactive distillation system for reactive distillation; when the concentration of hydroxylamine hydrochloride in the reaction solution reaches 7 to 14 mol/L, the solid obtained by crystallization and filtering is the product hydroxylamine hydrochloride, and the filtrate after crystallization and filtration is mixed with the water-rich phase of the distillate and recycled for absorbing the hydrogen chloride dry gas. The method utilizes hydrogen chloride dry gas as a raw material to prepare hydroxylamine hydrochloride, the process route is simple, the water content in the reaction solution is low, the energy consumption in arectification process is r