Method for preparing hydroxylamine hydrochloride by using hydrogen chloride dry gas
The invention relates to a method for preparing hydroxylamine hydrochloride by using hydrogen chloride dry gas. The method utilizes a mixture of a filtrate obtained by crystallization and filtering ofan oxime hydrolysis reaction and a water-rich phase of a distillate to absorb hydrogen chloride dry...
Gespeichert in:
Hauptverfasser: | , , , , |
---|---|
Format: | Patent |
Sprache: | chi ; eng |
Schlagworte: | |
Online-Zugang: | Volltext bestellen |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | The invention relates to a method for preparing hydroxylamine hydrochloride by using hydrogen chloride dry gas. The method utilizes a mixture of a filtrate obtained by crystallization and filtering ofan oxime hydrolysis reaction and a water-rich phase of a distillate to absorb hydrogen chloride dry gas, and the obtained absorption liquid and ketoxime are added to a reactive distillation system for reactive distillation; when the concentration of hydroxylamine hydrochloride in the reaction solution reaches 7 to 14 mol/L, the solid obtained by crystallization and filtering is the product hydroxylamine hydrochloride, and the filtrate after crystallization and filtration is mixed with the water-rich phase of the distillate and recycled for absorbing the hydrogen chloride dry gas. The method utilizes hydrogen chloride dry gas as a raw material to prepare hydroxylamine hydrochloride, the process route is simple, the water content in the reaction solution is low, the energy consumption in arectification process is r |
---|