Hydrodesulfurization catalyst of mesoporous ETS-10 zeolite carrier, preparation method and application thereof

The invention provides a hydrodesulfurization catalyst of a mesoporous ETS-10 zeolite carrier, a preparation method and application thereof. The catalyst is prepared from mesoporous ETS-10 zeolite loaded with at least two metal sulfides of Ni, Mo and W, wherein the mesoporous ETS-10 zeolite has a sp...

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Hauptverfasser:	XU WEICHI, WU XIANJUN, FANG LEI, ZHANG LEI, WEN GUANGMING, SHEN RUNSHENG, ZHANG GUOJIA, TAN MINGWEI, ZHANG QUANGUO, SONG JINHE, CONG LIRU, DONG CHUNMING, FU WENQIAN, GUO JINTAO, GUO LIYAN, XU TIEGANG, LIANG YU, WANG GANG, TANG TIANDI, CAI GUOREN, MA BAOLI, WANG DAN, ZHANG WENCHENG
Format:	Patent
Sprache:	chi ; eng
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CRACKING HYDROCARBON OILS FUELS LUBRICANTS METALLURGY MINERAL WAXES PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	The invention provides a hydrodesulfurization catalyst of a mesoporous ETS-10 zeolite carrier, a preparation method and application thereof. The catalyst is prepared from mesoporous ETS-10 zeolite loaded with at least two metal sulfides of Ni, Mo and W, wherein the mesoporous ETS-10 zeolite has a specific surface area of 250-420m /g and a mesoporous volume of 0.1-0.21cm /g. Active metal is loaded on ETS-10 zeolite by utilizing the special porous structure of mesoporous ETS-10, and the hydrodesulfurization catalyst with high activity is synthesized. 本发明提供了种介孔ETS-10沸石载体的加氢脱硫催化剂及其制备方法与应用，本发明的催化剂是介孔ETS-10沸石负载Ni、Mo、W中至少两种金属硫化物而制成，所述介孔ETS-10沸石的比表面积为250～420m/g，介孔孔容为0.1～0.21cm/g。本发明利用介孔ETS-10的特殊的孔道结构，将活性金属负载在ETS-10沸石上，合成了具有高活性的加氢脱硫催化剂。