Preparation method of blocked isocyanate modified quaternary ammonium silicone copolymer

The invention provides a preparation method of a blocked isocyanate modified quaternary ammonium silicone copolymer. The preparation method comprises the following steps: reacting epoxy-terminated polysiloxane and a compound containing tertiary amine groups, adding diisocyanate, polyether polyol or...

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Bibliographische Detailangaben
Hauptverfasser: GUO YULIANG, XIE SHUMING, YOU JIANPENG, YIN LIANG, ZHOU YAOLIANG, LIN WEIHONG, ZHANG JIANJUN, XIAO CHENGGUI
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides a preparation method of a blocked isocyanate modified quaternary ammonium silicone copolymer. The preparation method comprises the following steps: reacting epoxy-terminated polysiloxane and a compound containing tertiary amine groups, adding diisocyanate, polyether polyol or polyether amine to carry out a stepwise polymerization reaction, and finally adding a blocking agentfor blocking, thereby obtaining the quaternary ammonium salt-containing polyurethane modified silicone copolymer. Compared with polyether-modified polysiloxane in the prior art, the blocked isocyanate modified quaternary ammonium silicone copolymer disclosed by the invention has the advantages that the end position is provided with a blocked isocyanate group, blocking of isocyanate can be maintained at the room temperature, and the blocked isocyanate group is capable of de-blocking under suitable conditions. By achieving an electric charge effect or carrying out a cross-linking reaction withgroups on fabrics, the sto