Colorless terpene resin and preparation process thereof
The invention discloses colorless terpene resin and a preparation process thereof. According to the method, terpene materials are taken as raw materials, and crude products containing terpene resin are prepared through low temperature polymerization in aromatic solvent by taking AlCl3 as a main cata...
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Format: | Patent |
Sprache: | chi ; eng |
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Zusammenfassung: | The invention discloses colorless terpene resin and a preparation process thereof. According to the method, terpene materials are taken as raw materials, and crude products containing terpene resin are prepared through low temperature polymerization in aromatic solvent by taking AlCl3 as a main catalyst and chlorotrimethylsilane as a cocatalyst; the crude products containing the colorless terpeneresin are prepared through high-pressure hydrogenation under the action of metal catalysts after hot wash and centrifugal water removal are conducted; the catalysts are recovered by filtering, the colorless terpene resin is obtained by conducting reduced pressure distillation on filtrate, and substituted cyclanes, pinane or p-menthane and hydrogenated liquid terpene resin are simultaneously obtained. An adding manner of the two catalysts is that the main catalyst is added before the raw materials are added dropwisely, and the cocatalyst is added after dropwise adding of the raw materials is completed; the metal cataly |
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