Binuclear manganese(II) 2-fluorobenzoate one dimensional coordination polymer and preparation method thereof

The invention belongs to the fields of inorganic-organic hybrid materials, inorganic-organic framework materials and crystal engineering, and particularly relates to a binuclear manganese(II) 2-fluorobenzoate one dimensional coordination polymer. The binuclear manganese(II) 2-fluorobenzoate one dime...

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Bibliographische Detailangaben
Hauptverfasser: ZHANG BISONG, WU CHANGSHENG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention belongs to the fields of inorganic-organic hybrid materials, inorganic-organic framework materials and crystal engineering, and particularly relates to a binuclear manganese(II) 2-fluorobenzoate one dimensional coordination polymer. The binuclear manganese(II) 2-fluorobenzoate one dimensional coordination polymer has the following structural formula: [Mn2(4,4'-bpy)2(L)4]n, wherein 4,4'-bpy is 4,4'- dipyridyl, and HL is 2-fluorobenzoic acid. The polymer has the advantages that the compound has a three-dimensional framework structure with a variety of micropores, and has a potential application prospect in the aspects of adsorption, catalysis, etc. 本发明属于无机有机杂化材料、无机-有机框架材料和晶体工程学领域,尤其涉及种2-氟苯甲酸双核锰(II)维带状配位聚合物,其结构式如下:[Mn 2 (4,4'-bpy) 2 (L) 4 ]n;所述的 4,4'-bpy 为 4,4'-联吡啶,HL 为 2-氟苯甲酸;本发明的优点:该化合物具有多种微孔组成的三维框架结构,在吸附、催化等方面具有潜在的应用前景。