Y/EU-1/SBA-15/ASA/MOF composite material and preparation method thereof

The invention provides a Y/EU-1/SBA-15/ASA/MOF composite material and a preparation method thereof. The method comprises the following steps: synthesizing a guiding agent, and synthesizing a small grain size Y-type molecular sieve by adopting a hydrothermal crystallization method; adding surfactant,...

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Hauptverfasser: ZHANG CHUNQING, QIN LIHONG, WANG LIANG, CONG LIRU, JIN LILI, YUAN JICHENG, YU CHUNMEI, XIE FANGMING, ZHANG YINGHUA, TIAN RAN, LI HAIYAN, CHEN CHAO, ZHANG QUANGUO, WANG FUCUN, DONG CHUNMING, LYU QIAN, ZHANG ZHIHUA, GUO JINTAO, SUN FAMIN, SHAO ZHENGHONG, LI XUN, ZHANG WENCHENG, NI SHURONG, XI XIAOLI, WANG YAN
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides a Y/EU-1/SBA-15/ASA/MOF composite material and a preparation method thereof. The method comprises the following steps: synthesizing a guiding agent, and synthesizing a small grain size Y-type molecular sieve by adopting a hydrothermal crystallization method; adding surfactant, EU-1 and SBA-15 molecular sieve slurry and alkaline aluminum-source solution into the slurry containing molecular sieve, and washing, drying and roasting the product to obtain Y/EU-1/SBA-15/ASA complex; uniformly mixing and stirring with a metal salt aqueous solution, and drying to obtain a metal-loaded Y/EU-1/SBA-15/ASA composite material; adding carboxyl-containing organic acid into an organic solvent of alcohol and amide, and uniformly mixing to obtain organic mixture; and adding the metal-loaded Y/EU-1/SBA-15/ASA material into the organic mixture, uniformly stirring, and reacting to obtain the Y/EU-1/SBA-15/ASA/MOF composite material. 本发明提供了种Y/EU-1/SBA-15/ASA/MOF复合材料及其制备方法,包括:先合成导向剂,采用水热晶化法合成小晶粒Y型分子筛,然后在含分子筛的浆