Asymmetric photoelectric active thiacalixarene [4] acceptor molecule and compounding method thereof

The invention discloses an asymmetric photoelectric active thiacalixarene [4] acceptor molecule and a compounding method thereof. The method is characterized by successfully compounding the asymmetric photoelectric active thiacalixarene [4] acceptor molecule containing ferrocene and rhodamine b grou...

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Hauptverfasser: LYU XUEXIN, ZHAO LE, JIANG GUOJING, GUO DIANSHUN, GUO YUSHUANG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses an asymmetric photoelectric active thiacalixarene [4] acceptor molecule and a compounding method thereof. The method is characterized by successfully compounding the asymmetric photoelectric active thiacalixarene [4] acceptor molecule containing ferrocene and rhodamine b groups by successively introducing an electrochemical probe and a fluorescence probe into a thiacalixarene [4] structure platform by utilizing asymmetric design and then performing stepping selective acylation reaction of thiacalixarene [4]-1,3-diamine. The technique according to the invention supplies a new method for designing and compounding the asymmetric photoelectric active thiacalixarene [4] acceptor molecule with photoresponse center and electroresponse center, establishes a basis for realizing the photoelectric two-channel response detection for the acceptor molecule and has significance in expanding the application thereof in super-molecular recognition. 本发明公开了种不对称光电活性硫杂杯[4]芳烃受体分子及其合成方法。其特色是利用不对称设计将电化学探针和荧光探针