Comprehensive recovery and utilization method for waste vanadium catalyst

The invention discloses a comprehensive recovery and utilization method for a waste vanadium catalyst. The method comprises the steps that water leaching and reductive acid leaching are sequentially conducted on the waste vanadium catalyst; silicon is separated and recycled by being prepared into so...

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Hauptverfasser: CAO MING, ZHAN GUIRONG, LOU TONGFANG, SHI ZHAOZHONG, HAO XICAI, JI HONG
Format: Patent
Sprache:chi ; eng
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Beschreibung
Zusammenfassung:The invention discloses a comprehensive recovery and utilization method for a waste vanadium catalyst. The method comprises the steps that water leaching and reductive acid leaching are sequentially conducted on the waste vanadium catalyst; silicon is separated and recycled by being prepared into sodium silicate through alkaline leaching in a residue leaching mode; single-stage extraction is conducted on leachate through saponification P204, vanadium and potassium are extracted and separated through vanadium extraction technologies of tail liquid concentration and separate re-extraction, potassium is separated by preparing potassium sulphate from raffinate through evaporation and concentration, and vanadium is recycled by preparing vanadium pentoxide from an extraction phase through the processes of back extraction, vanadium precipitation, calcination and the like. Through the extremely high selection characteristic of the saponification P204, not only are the extraction capacity, the utilization rate and the