Novel porphyrin compound as well as preparation method and application thereof

The invention belongs to the technical field of organic compound synthesis and discloses a novel porphyrin compound as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly, synthesizing Meso-tetraphenylporphyrin in the presence of propio...

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Hauptverfasser: YUAN JIAN, TONG SHANLING, YAN YAN, WU YAHONG, LIN HUI
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention belongs to the technical field of organic compound synthesis and discloses a novel porphyrin compound as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly, synthesizing Meso-tetraphenylporphyrin in the presence of propionic acid by utilizing benzaldehyde and pyrrole; secondly, taking the Meso-tetraphenylporphyrin as a raw material and selecting a dichloromethane/chloroform system as a mixed solvent, so as to synthesize 5-(4-chloromethyl phenyl)-10,15,20-triphenylporphyrin; enabling the 5-(4-chloromethyl phenyl)-10,15,20-triphenylporphyrin and hexamethylenetetramine to react in a chloroform solvent and refluxing in acetic acid; after separating and purifying through column chromatography, obtaining a novel compound 5-(4-chloromethyl phenyl)-10,15,20-phenylporphyrin. 本发明属于有机化合物合成的技术领域,公开了种新型卟啉类化合物及其制备方法和应用。制备方法包括步骤:首先利用苯甲醛和吡咯在丙酸的环境下合成Meso-四苯基卟啉,然后采用Meso-四苯基卟啉为原料,选用二氯甲烷/氯仿体系为混合溶剂,合成5-(4-氯甲基苯基)-10,15,20-三苯基卟啉,再将5-(4-氯甲基苯基)-10,15,20-三苯