A surface-amphiphilic nanometer composite sulfide catalyst, a preparing method thereof and applications of the catalyst
The invention relates to a surface-amphiphilic nanometer composite sulfide hydrogenation catalyst, a preparing method thereof and applications of the catalyst. A nickel source and/or a cobalt source and/or an iron source, a sulfur-containing molybdenum source and/or a sulfur-containing tungsten sour...
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Format: | Patent |
Sprache: | chi ; eng |
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Zusammenfassung: | The invention relates to a surface-amphiphilic nanometer composite sulfide hydrogenation catalyst, a preparing method thereof and applications of the catalyst. A nickel source and/or a cobalt source and/or an iron source, a sulfur-containing molybdenum source and/or a sulfur-containing tungsten source, a sulfur source, an ionic liquid, a reductant and deionized water are prepared into an initial reaction mixture, the initial reaction mixture is crystallized in a sealed autoclave under hydro-thermal conditions, and the catalyst is obtained after product separation. The ionic liquid is used in the synthetic system, and the prepared sulfide has a nanometer size and surface amphipathicity, and has extremely good dispersibility and catalytic activity in polar and nonpolar catalytic systems. The catalyst shows extremely good catalytic activity in suspended-bed hydrogenation deasphalting, hydrodesulfurization, hydro-denitrification, aromatic hydrocarbon hydrogenation, and the like of coal tar, heavy oil, extra-heavy |
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