A surface-amphiphilic nanometer composite sulfide catalyst, a preparing method thereof and applications of the catalyst

The invention relates to a surface-amphiphilic nanometer composite sulfide hydrogenation catalyst, a preparing method thereof and applications of the catalyst. A nickel source and/or a cobalt source and/or an iron source, a sulfur-containing molybdenum source and/or a sulfur-containing tungsten sour...

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Hauptverfasser: WANG DONG'E, LI PENG, XU RENSHUN, MA HUAIJUN, WANG CONGXIN, WANG BINGCHUN, QU WEI, TIAN ZHIJIAN, PAN ZHENDONG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention relates to a surface-amphiphilic nanometer composite sulfide hydrogenation catalyst, a preparing method thereof and applications of the catalyst. A nickel source and/or a cobalt source and/or an iron source, a sulfur-containing molybdenum source and/or a sulfur-containing tungsten source, a sulfur source, an ionic liquid, a reductant and deionized water are prepared into an initial reaction mixture, the initial reaction mixture is crystallized in a sealed autoclave under hydro-thermal conditions, and the catalyst is obtained after product separation. The ionic liquid is used in the synthetic system, and the prepared sulfide has a nanometer size and surface amphipathicity, and has extremely good dispersibility and catalytic activity in polar and nonpolar catalytic systems. The catalyst shows extremely good catalytic activity in suspended-bed hydrogenation deasphalting, hydrodesulfurization, hydro-denitrification, aromatic hydrocarbon hydrogenation, and the like of coal tar, heavy oil, extra-heavy