Sulfonated polyarylether sulfone copolymer containing pyridine group as well as preparation method and application of sulfonated polyarylether sulfone copolymer

The invention belongs to the field of high polymer materials and particularly relates to sulfonated polyarylether sulfone containing a pyridine group and a preparation method of the sulfonated polyarylether sulfone. According to the preparation method, dichloropyridine such as 3,5-dichloropyridine i...

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Hauptverfasser: LU AI, GENG CHENGZHEN, YU FENGMEI, ZHANG QIAN, LI YE, SUN SUMING
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention belongs to the field of high polymer materials and particularly relates to sulfonated polyarylether sulfone containing a pyridine group and a preparation method of the sulfonated polyarylether sulfone. According to the preparation method, dichloropyridine such as 3,5-dichloropyridine is taken as a monomer, and the feeding proportion of sulfonated monomers to non-sulfonated monomers is adjusted, so as to prepare polyarylether sulfone with different sulfonating degrees by virtue of nucleophilic condensation polymerization; and meanwhile, the feeding proportion of pyridine monomers is adjusted, so as to prepare sulfonated polyarylether sulfone with different pyridine content. A sulfonated polyarylether sulfone copolymer film containing the pyridine group has good dimensional stability, chemical stability and alcohol-rejecting ability and further has potential application prospect in the field of fuel cell polymer electrolyte membranes. 本发明属于高分子材料领域,具体涉及种含吡啶基团的磺化聚芳醚砜及其制备方法。本发明以3,5-二氯吡啶等二氯吡啶为单体,通过调整磺