Three-dimensional expansion skeleton copper iodide material having 27-MR oversized pore passages and preparation method thereof

The invention belongs to the technical field of synthesis of inorganic microporous materials and organic templates, and relates to a three-dimensional expansion skeleton copper iodide material having 27-MR oversized pore passages and a preparation method thereof. The preparation method comprises the following steps of carrying out in-situ alkylated modification on 2,4,6-tripyridyl-1,3,5triazine, thus generating N,N,N-trimethyl-2,4,6-tripyridyl-1,3,5triazine positive ions; realizing the preparation of a first three-dimensional expansion skeleton copper iodide material having the 27-MR oversized pore passages The three-dimensional expansion skeleton copper iodide material having the 27-MR oversized pore passages and the preparation method thereof, disclosed by the invention, have the advantages that a preparation technology is simple, the operation is easy, and an important application prospect in the fields of macromolecule separation and adsorption, ion exchange and industrial catalysis is obtained. 本发明属于无机微孔