Amination process improvement method for PP-ST-DVB-based strong base ion exchange fibers
The invention discloses an amination process improvement method for PP-ST-DVB-based strong base ion exchange fibers. The method comprises the following steps: adding a small amount of water into PP-ST-DVB fibers containing benzyl chloride or chloroacetyl functional groups, uniformly turning, and add...
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Format: | Patent |
Sprache: | chi ; eng |
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Zusammenfassung: | The invention discloses an amination process improvement method for PP-ST-DVB-based strong base ion exchange fibers. The method comprises the following steps: adding a small amount of water into PP-ST-DVB fibers containing benzyl chloride or chloroacetyl functional groups, uniformly turning, and adding the fibers into a horizontal reaction kettle in a wet state; carrying out a neutralization reaction between trimethylamine hydrochloride and solution obtained by dissolving NaOH solids to release trimethylamine gas; allowing the trimethylamine gas to enter the reaction kettle through gas, and rapidly aminating under heating and high-pressure conditions; after the reaction is ended, volatilizing the trimethylamine on the fiber surface as much as possible under high-speed rotation of an inner cylinder of the horizontal reaction kettle and heating and high-pressure conditions, condensing and recovering most of the trimethylamine gas for continuous use, and absorbing a small amount of trimethylamine gas by dilute s |
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