C8 arene isomerization catalyst and preparation method thereof

The invention relates to a C8 arene isomerization catalyst, which comprises a composite carrier and VIII group metal loaded on the composite carrier, wherein the content of the VIII group metal is 0.01-1.0 mass percentage which is calculated by taking a dry basis carrier as a benchmark, the composit...

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Bibliographische Detailangaben
Hauptverfasser: Kang Chenglin, Gu Haohui, Zhou Zhenhuan, Long Jun, Wu Wei
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention relates to a C8 arene isomerization catalyst, which comprises a composite carrier and VIII group metal loaded on the composite carrier, wherein the content of the VIII group metal is 0.01-1.0 mass percentage which is calculated by taking a dry basis carrier as a benchmark, the composite carrier comprises 1-12 mass percentage of pre-treated ZSM-5 zeolite or ZSM-11 zeolite, 1-38 mass percentage of mordenite and 50-98 mass percentage of alumina, a pretreatment method is characterized in that water vapor is used for processing HZSM-5 zeolite or HZSM-11 zeolite, or is used for performing sodion anti-commutation on the HZSM-5 zeolite or HZSM-11 zeolite. The catalyst is used for a C8 arene isomerization reaction, has high isomerization activity and C8 hydrocarbon yield, and can increase the p-xylene output. 种C芳烃异构化催化剂,包括复合载体和负载于复合载体上的以干基载体基准计算的含量为0.01~1.0质量%的Ⅷ族金属,所述的复合载体包括1~12质量%的经预处理的ZSM-5沸石或ZSM-11沸石、1~38质量%的丝光沸石和50~98质量%的氧化铝,所述的预处理方法为用水蒸汽处理HZSM-5沸石或HZSM-11沸石,或对HZSM-5沸石或HZSM-11沸石进行钠离子反交换。该催化剂用于C芳烃异构化反