Preparation method of pore filling type molecule/ion double-site imprinted polymer

Belonging to the technical field of environment functional material preparation, the invention provides a preparation method of a pore filling type molecule/ion double-site imprinted polymer. The method includes: firstly modifying solid silica spheres into stable particles, then preparing a Pickerin...

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Bibliographische Detailangaben
Hauptverfasser: LIU SHUCHENG, YAO JUNTONG, ZHU HENGJIA, ZHOU YONGCHAO, PAN JIANMING, YUAN DONG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:Belonging to the technical field of environment functional material preparation, the invention provides a preparation method of a pore filling type molecule/ion double-site imprinted polymer. The method includes: firstly modifying solid silica spheres into stable particles, then preparing a Pickering high internal phase emulsion's imprinted polymer (M-IIPs) with ion and molecule dual imprinting functions by ATRP molecular imprinting technology; and performing a series of treatment to obtain an adsorbent, and applying the adsorbent to selective recognition and separation of lambda-cyhalothrin (LC) and copper ions in a water solution. The molecule/ion dual recognition molecularly imprinted material prepared by the method provided by the invention has good thermal stability, high adsorption capacity, and has a hierarchical pore structure, and obvious LC molecule and copper ion recognition performance. 本发明提供种孔道填充型分子/离子双位点印迹聚合物的制备方法,属环境功能材料制备技术领域;本发明首先对实心硅球进行了改性做成稳定粒子,紧接着通过ATRP分子印迹技术制备Pickering高内相乳液带有离子和分子双重印迹功能的印