Ionic type phosphorescent Ag6Cu complex and its preparation method and use

The invention relates to an ionic type phosphorescent Ag6Cu complex and its preparation method and use. The ionic type phosphorescent Ag6Cu complex has a structural formula of [Ag6Cu{HC(PPh2)3}2(C[triple-bond]CR)3{Ph2P(=X)X}3]A1/n, wherein X represents the same or different groups of O, S and Se, R...

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Hauptverfasser: XU LIANGJIN, CHEN ZHONGNING, SHU HUIXING, WANG JINYUN
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CHEN ZHONGNING
SHU HUIXING
WANG JINYUN
description The invention relates to an ionic type phosphorescent Ag6Cu complex and its preparation method and use. The ionic type phosphorescent Ag6Cu complex has a structural formula of [Ag6Cu{HC(PPh2)3}2(C[triple-bond]CR)3{Ph2P(=X)X}3]A1/n, wherein X represents the same or different groups of O, S and Se, R represents the same or different groups of aryl, heterocyclic aryl and -aryl-heterocyclic aryl, the heterocyclic aryl and aryl can be replaced through one or more substituents, the substituents are respectively selected from alkyl, alkenyl, alkynyl, alkyloxy, amino, halogen, halogenated alkyl and aryl, and A represents ClO, PF, SbF, BF or SiF6 and n is 1 or 2. The invention also relates to an organic light-emitting diode and its preparation method and use. The phosphorescent metal complex is a doped luminescent layer. The prepared organic light-emitting diode produces high performance organic electroluminescence and can be used for panel display.
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The ionic type phosphorescent Ag6Cu complex has a structural formula of [Ag6Cu{HC(PPh2)3}2(C[triple-bond]CR)3{Ph2P(=X)X}3]<+>A1/n, wherein X represents the same or different groups of O, S and Se, R represents the same or different groups of aryl, heterocyclic aryl and -aryl-heterocyclic aryl, the heterocyclic aryl and aryl can be replaced through one or more substituents, the substituents are respectively selected from alkyl, alkenyl, alkynyl, alkyloxy, amino, halogen, halogenated alkyl and aryl, and A represents ClO<4->, PF<6->, SbF<6->, BF<4-> or SiF6<2-> and n is 1 or 2. The invention also relates to an organic light-emitting diode and its preparation method and use. The phosphorescent metal complex is a doped luminescent layer. 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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
ADHESIVES
BASIC ELECTRIC ELEMENTS
CHEMISTRY
DYES
ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
ELECTRICITY
MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
ORGANIC CHEMISTRY
PAINTS
POLISHES
SEMICONDUCTOR DEVICES
title Ionic type phosphorescent Ag6Cu complex and its preparation method and use
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