Ionic type phosphorescent Ag6Cu complex and its preparation method and use

The invention relates to an ionic type phosphorescent Ag6Cu complex and its preparation method and use. The ionic type phosphorescent Ag6Cu complex has a structural formula of [Ag6Cu{HC(PPh2)3}2(C[triple-bond]CR)3{Ph2P(=X)X}3]A1/n, wherein X represents the same or different groups of O, S and Se, R...

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Bibliographische Detailangaben
Hauptverfasser:	XU LIANGJIN, CHEN ZHONGNING, SHU HUIXING, WANG JINYUN
Format:	Patent
Sprache:	chi ; eng
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ADHESIVES BASIC ELECTRIC ELEMENTS CHEMISTRY DYES ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR ELECTRICITY MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC CHEMISTRY PAINTS POLISHES SEMICONDUCTOR DEVICES
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Beschreibung
Zusammenfassung:	The invention relates to an ionic type phosphorescent Ag6Cu complex and its preparation method and use. The ionic type phosphorescent Ag6Cu complex has a structural formula of [Ag6Cu{HC(PPh2)3}2(C[triple-bond]CR)3{Ph2P(=X)X}3]A1/n, wherein X represents the same or different groups of O, S and Se, R represents the same or different groups of aryl, heterocyclic aryl and -aryl-heterocyclic aryl, the heterocyclic aryl and aryl can be replaced through one or more substituents, the substituents are respectively selected from alkyl, alkenyl, alkynyl, alkyloxy, amino, halogen, halogenated alkyl and aryl, and A represents ClO, PF, SbF, BF or SiF6 and n is 1 or 2. The invention also relates to an organic light-emitting diode and its preparation method and use. The phosphorescent metal complex is a doped luminescent layer. The prepared organic light-emitting diode produces high performance organic electroluminescence and can be used for panel display.