Metal organic framework material based on lead nitrate and application thereof

The invention relates to a metal organic framework material based on lead nitrate and application thereof. The technical scheme is that metal salt Pb(NO3)2, ligand H4BPTC and a solvent N,N-dimethylacetamide are placed in a container, ultrasonic oscillation is performed until the metal salt and the l...

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Bibliographische Detailangaben
Hauptverfasser:	ZHANG YUYANG, GENG ZHI, LUO YANJUAN, DING LINLIN
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	The invention relates to a metal organic framework material based on lead nitrate and application thereof. The technical scheme is that metal salt Pb(NO3)2, ligand H4BPTC and a solvent N,N-dimethylacetamide are placed in a container, ultrasonic oscillation is performed until the metal salt and the ligand are evenly scattered into the solvent; the solvent is sealed and then placed in an oven to stand for 72 h at 85 DEG C, white cube blocky crystal is obtained, washed, filtered and dried, and a target product is obtained. A method for preparing the metal organic framework material is simple, the metal organic framework material is stable in structure and has a good three-dimensional pore structure, the silicon cyanation can be catalyzed efficiently, reaction substrate aromatic aldehyde has size selectivity, and the catalytic reaction is performed on the anhydrous and oxygen-free conditions.