Treatment method and apparatus of dimethyl sulfoxide production tail gas

The invention relates to waste gas treatment techniques and provides a treatment method of dimethyl sulfoxide production tail gas. The treatment method includes: A, cooling the tail gas, condensing methyl mercaptan, dimethyl sulfide and methyl alcohol into mixed solution A, and keeping most hydrogen...

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Hauptverfasser: GUO KEXIONG, HUANG YUNXIA, GUO-MAO XIAOCHUN, HUANG FEI, MA LEI
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creator GUO KEXIONG
HUANG YUNXIA
GUO-MAO XIAOCHUN
HUANG FEI
MA LEI
description The invention relates to waste gas treatment techniques and provides a treatment method of dimethyl sulfoxide production tail gas. The treatment method includes: A, cooling the tail gas, condensing methyl mercaptan, dimethyl sulfide and methyl alcohol into mixed solution A, and keeping most hydrogen sulfide gaseous; B, mixing the mixed solution A and water, and separating the methyl alcohol easily soluble in water so as to obtain mixed solution B; C, stripping hydrogen sulfide in the mixed solution B so as to obtain mixed solution C; D, heating the mixed solution C to be gaseous, absorbing the hydrogen sulfide in mixed gas through a desulfurizing agent, and performing fine desulfurization; and E, introducing gas obtained in the step D into sodium hydroxide solution, and absorbing the methyl mercaptan to obtain disulfide methyl ether gas. A treatment apparatus of the dimethyl sulfoxide production tail gas is further provided; the treatment apparatus comprises a cooler, a methyl alcohol extraction column, a striping desulfurizing column, a heater, an absorption desulfurizing reactor and an absorption column communicated in order through a pipeline. The treatment method and apparatus is capable of recovering various components in the tail gas, economic benefit is increased, and environmental pollution is decreased.
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The treatment method includes: A, cooling the tail gas, condensing methyl mercaptan, dimethyl sulfide and methyl alcohol into mixed solution A, and keeping most hydrogen sulfide gaseous; B, mixing the mixed solution A and water, and separating the methyl alcohol easily soluble in water so as to obtain mixed solution B; C, stripping hydrogen sulfide in the mixed solution B so as to obtain mixed solution C; D, heating the mixed solution C to be gaseous, absorbing the hydrogen sulfide in mixed gas through a desulfurizing agent, and performing fine desulfurization; and E, introducing gas obtained in the step D into sodium hydroxide solution, and absorbing the methyl mercaptan to obtain disulfide methyl ether gas. 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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
TRANSPORTING
title Treatment method and apparatus of dimethyl sulfoxide production tail gas
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