Composite molecular sieve catalyst for preparation of gasoline from methanol and preparation method thereof

The present invention provides a composite molecular sieve catalyst for preparation of gasoline from methanol and a preparation method thereof. The method is as follows: ZSM-5 molecular sieve and NaY molecular sieve are added into a tetrapropyl quaternary ammonium salt and inorganic base mixed aqueo...

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Hauptverfasser: ZHANG XIANGJING, TAO RAN, LU CHIJIE, HU YONGQI, ZHANG LIZHE, CHEN GUOGANG, LIU YUMIN, ZHANG QINGJIE, MA RENJUAN
Format: Patent
Sprache:eng
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Zusammenfassung:The present invention provides a composite molecular sieve catalyst for preparation of gasoline from methanol and a preparation method thereof. The method is as follows: ZSM-5 molecular sieve and NaY molecular sieve are added into a tetrapropyl quaternary ammonium salt and inorganic base mixed aqueous alkali solution for high-temperature reaction, filtration and roasting to make a much-level molecular sieve, and the composite molecular sieve catalyst can be obtained by hydrogen type replacement of the much-level molecular sieve and an ammonium nitrate solution and extruding forming with a binder which is added with a strength aid. The preparation method is simple and low- cost, and the catalyst for the reaction of preparation of gasoline from methanol has high gasoline yield, high catalyst mechanical strength, long life and other advantages.