Method for synthesizing linear high molecular weight polyphenylene sulfide

The invention discloses a method for synthesizing linear high molecular weight polyphenylene sulfide and belongs to the technical field of chemical material. The method comprises the following steps: by taking sodium sulphide and dichloro diphenyl as raw materials, synthesizing the linear high molecular weight polyphenylene sulfide (PPP) resin through a solution polycondensation method and a secondary polymerization process in a compound solvent and a cosolvent system. The method is simple in process and convenient to operate; the product has a high molecular weight linear structure; in the whole polymerization process, the molecular weight is controllable. Compared with the prior art, the method has the advantages of good solvent system dissolving property, low salt content and easy separation. The monomer reactivity of the linear polymerization reaction is high and the chain extension is easy to process. The dosage of the alkali metal or the alkaline earth chloride is few and the metal ion can be easily washed. The linear high molecular weight polyphenylene sulfide does not have irritant or carcinogenic property and is environmentally friendly to operate.