Selective oxidation method of light olefins

The invention relates to a selective oxidation method of light olefins. According to the selective oxidation method, reaction raw materials propylene, water, and air are subjected to preheating using a preheater at a temperature higher than 120 DEG C, and then are delivered into a fixed bed single p...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: ZHAI YUEQIN, LIU JUNBAO, ZHAO HUIHUI, JIA HUIQING, ZHANG CUILAN, TANG YANWEN, CHEN GENPING, HUANG SHIYING, QIN PENG, WANG FANG, DA MINFENG, WEI YULI, WU YI, LI XIAOYIN, GENG ZHANJIE
Format: Patent
Sprache:eng
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The invention relates to a selective oxidation method of light olefins. According to the selective oxidation method, reaction raw materials propylene, water, and air are subjected to preheating using a preheater at a temperature higher than 120 DEG C, and then are delivered into a fixed bed single pipe reactor; and salt bath heating is carried out. The fixed bed single pipe reactor is filled with a propylene selective oxidation catalyst; the selective oxidation catalyst contains molybdenum, bismuth, iron, nickel, cobalt, and tungsten, and also contains magnesium-based lanthanum hexaaluminate. Structure of the selective oxidation catalyst is stable; loss of the active ingredients, such as molybdenum, is not easily caused; phase transformation of the active phases is not easily caused; and selectivity and yield of target products are improved.