Recycling method for waste CO sulfur-tolerant shift catalysts

The invention relates to a recycling method for waste CO sulfur-tolerant shift catalysts. The recycling method comprises the following steps: crushing the waste CO sulfur-tolerant shift catalysts, milling the crushed waste CO sulfur-tolerant shift catalysts, Fe(OH)3 and Cr(OH)3 together for 1-2 hours to be made into particles through a 8-mesh screen cloth, roasting the particles for 6-8 hours at the low temperature of 250-300 DEG C, cooling the roasted particles, and then tabletting and shaping the cooled particles to obtain CO high-temperature shift catalysts. Through detection according to the national chemical industry standard HG/T 3546-2011, all the performance indexes are much higher than quality technology requirements of B116 type CO high-temperature shift catalysts which are sold in the market. Through the adoption of the recycling method, the resource utilization rate of the waste CO sulfur-tolerant shift catalysts reaches 100%, sulfur in waste catalysts does not need to be removed, SO2 waste gas, NO waste gas and NO2 waste gas are not generated in the whole recovery process, and waste liquid and waste residues are not generated, so that the purposes of zero secondary pollution and zero new 'three wastes' are really realized, and not only are molybdenum sources saved, but also the recycling method is environmental-friendly.