Control synthesis and application of aryl organic multidentate ligand-cucurbituril porous framework polymer
The invention relates to control synthesis and application of an aryl organic multidentate ligand-cucurbituril porous framework polymer, and belongs to a multidimensional multi-cavity cucurbituril organic polymer and a synthetic method and application. The aryl organic multidentate ligand-cucurbitur...
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Zusammenfassung: | The invention relates to control synthesis and application of an aryl organic multidentate ligand-cucurbituril porous framework polymer, and belongs to a multidimensional multi-cavity cucurbituril organic polymer and a synthetic method and application. The aryl organic multidentate ligand-cucurbituril porous framework polymer is BTB-Q[6]-NH4 and BTB-Q[6]-Cs. Firstly, BTB-Q[6]-Cs is synthesized under a certain condition, then BTB-Q[6]-Cs is dissolved in diluted hydrochloric acid for obtaining BTB-Q[6]-NH4, and in an ammonia solution with a certain concentration and in the presence of Cs, BTB-Q[6]-NH4 is converted into BTB-Q[6]-Cs, so that separation and enrichment of Cs are realized. The synthetic method is performed at normal temperature under normal pressure, and has the characteristics of simple and rapid operation, high efficiency, high yield and the like. |
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