Method for extracting vanadium from high-calcium and high-phosphorus vanadium slag

The invention provides a method for extracting vanadium from high-calcium and high-phosphorus vanadium slag. The method comprises the following steps of: crushing the high-calcium and high-phosphorus vanadium slag, and adding concentrated hydrochloric acid into the crushed high-calcium and high-phos...

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Hauptverfasser: SUN ZHAOHUI, YIN ZHAOQIAN
Format: Patent
Sprache:chi ; eng
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Beschreibung
Zusammenfassung:The invention provides a method for extracting vanadium from high-calcium and high-phosphorus vanadium slag. The method comprises the following steps of: crushing the high-calcium and high-phosphorus vanadium slag, and adding concentrated hydrochloric acid into the crushed high-calcium and high-phosphorus vanadium slag to carry out activating treatment, wherein the CaO/V2O5 content in the high-calcium and high-phosphorus vanadium slag is higher than 1, and the phosphorus content in the high-calcium and high-phosphorus vanadium slag is higher than 0.15wt%; filtering and separating to obtain a supernatant and low-calcium and low-phosphorus vanadium slag; regulating the pH value of the supernatant to 2.5-10, filtering to obtain ferric hydroxide, evaporating and concentrating the filtered solution, and then, cooling and crystallizing to obtain calcium chloride; roasting the low-calcium and low-phosphorus vanadium slag within the temperature range of 800-1500 DEG C to obtain clinker, and then, carrying out acid le