Nitrogen heterocyclic BODIPY compound and synthesis method thereof

The invention discloses a nitrogen heterocyclic BODIPY compound and a synthesis method thereof. The structural formula of the compound refers to patent specification, wherein each of R1 and R2 is independently selected from one of Cl, Br, I, methyl and ethyl, n is within the range of 1 to 5, prefera...

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Hauptverfasser: ZHANG PING, GAO NAIXUN, JIAO LIJUAN, DING YIN
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses a nitrogen heterocyclic BODIPY compound and a synthesis method thereof. The structural formula of the compound refers to patent specification, wherein each of R1 and R2 is independently selected from one of Cl, Br, I, methyl and ethyl, n is within the range of 1 to 5, preferably n is within the range of 1 to 3, and m is within the range of 1 to 5. The synthesis method comprises the following steps: reacting halogenated benzaldehyde or hydrocarbon generation of benzaldehyde with p-methoxy acetophenone under the alkaline condition to obtain the product a, then performing reflux reaction on the obtained product a with ethylene diamine and nitromethane to obtain the product b, performing reflux reaction on the obtained product b with ammonium acetate to obtain the product c, and reacting the obtained product c with triethylamine and boron trifluoride solution to obtain the product d, which is the target product nitrogen heterocyclic BODIPY compound. The nitrogen heterocyclic BODIPY compoun