Method for preparing manganese chloride, ferrous chloride and calcium chloride from manganese tailings

The invention provides a method for preparing manganese chloride, ferrous chloride and calcium chloride from manganese tailings, comprising the following steps: crushing the manganese tailings into particles of 80-100 meshes, mixing and reacting with excessive hydrochloric acid solution, filtering t...

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1. Verfasser: XIE SHANQING
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides a method for preparing manganese chloride, ferrous chloride and calcium chloride from manganese tailings, comprising the following steps: crushing the manganese tailings into particles of 80-100 meshes, mixing and reacting with excessive hydrochloric acid solution, filtering the reactant liquid to obtain filtrate mainly containing ferrous chloride, magnesium chloride and manganese chloride; adding excessive sodium sulfide to the filtrate, and filtering the reactant liquid to obtain filter cake containing manganese sulfide, ferrous sulfide and calcium sulfide; reacting the filter cake containing manganese sulfide, ferrous sulfide and calcium sulfide with the hydrochloric acid solution to obtain reactant liquid containing manganese chloride, ferrous chloride and calcium chloride; and delivering the reactant liquid containing manganese chloride, ferrous chloride and calcium chloride into a reduced pressure distiller for performing reduced pressure distillation to obtain a saturated solutio