Conductive polymer composite with super hydrophobicity and preparation method thereof

The invention provides a conductive polymer composite with super hydrophobicity and preparation method thereof, relating to a polymer functional material. The polymer composite is composed of polymer material and polymer microsphere in nano structure, the polymer microsphere in nano structure is taken as core, and the surface is coated with the conductive polymer material in nano network structure. Polymer microsphere and cationic surfactant are dissolved into water to obtain solution A; conductive polymer monomer is dissolved into organic solvent and then added into the solution A, so as to obtain solution B; oxidant is dissolved into inorganic acid and then added into the solution B, reaction is carried out, and product is obtained. Competitive absorption of protonated anline monomer or pyrrole monomer with the cationic surfactant on the polymer microsphere surface is utilized, polymerization on aline or prrole monomer is carried out in the limited area of the microsphere surface, thus obtaining complex nan