New reaction with primary allylic alcohols

New reaction with primary allylic alcohols

The invention relates to a process of reacting a primary allylic alcohol with a compound containing a) a metal selected from the group consisting of Ag, Au, Ce, Mn, Ni, Ru, Re, Zn and Co preferably Ag and b) an oxidant like TEMPO (2,2',6,6'-tetra-methylpiperidin- 1-oxyl) or its derivates a...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: BONRATH WERNER, ECKHARDT JEAN-FRANCOIS, HINZE RAMONA, EGGERSDORFER MANFRED L, HOELDERICH WOLFGANG F
Format: Patent
Sprache:chi ; eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:The invention relates to a process of reacting a primary allylic alcohol with a compound containing a) a metal selected from the group consisting of Ag, Au, Ce, Mn, Ni, Ru, Re, Zn and Co preferably Ag and b) an oxidant like TEMPO (2,2',6,6'-tetra-methylpiperidin- 1-oxyl) or its derivates and c) a co-oxidants selected from the group of peroxodisulfates (PDS), H2SO5, H2O2, NaOCl, O2, KOCl, and air.