Method for preparing allyl surface-active macromonomer

The invention discloses a method for preparing an allyl surface-active macromonomer, which is characterized by comprising the following steps: adding 20 portions of alkylphenol polyoxyethylene ether (CmH2m+1-C6H4-O-(CH2CH2O)nH, n is equal to 1 to 60, and m is equal to 1 to 20), 10 to 900 portions of...

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Bibliographische Detailangaben
Hauptverfasser: PENG XIUHUA, ZHONG CHUANRONG, WANG SHIGAO
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses a method for preparing an allyl surface-active macromonomer, which is characterized by comprising the following steps: adding 20 portions of alkylphenol polyoxyethylene ether (CmH2m+1-C6H4-O-(CH2CH2O)nH, n is equal to 1 to 60, and m is equal to 1 to 20), 10 to 900 portions of solvent and 0.1 to 15 portions of catalyst into a three-mouth reaction flask with a reflux condensation device, and reacting the mixture for 1 hour under stirring at the room temperature; increasing temperature to 30 to 95 DEG C, adding 0.5 to 20 portions of allyl chloride into the reaction product, and continuously reacting for 6 to 48 hours; distilling the reaction product under reduced pressure to remove the solvent so as to obtain a crude product; and performing silica gel column chromatographic separation to obtain allyl alkylphenol polyoxyethylene ether with the yield of 70 to 95 percent. The allyl alkylphenol polyoxyethylene ether has excellent surface activity, and can be directly used as a surfactant. A w