Catalyst for producing 1,2-cyclohexane dicarboxylic acid diesters

The invention provides a catalyst for converting diisononyl phthalate, diisooctyl phthalate, dibutyl phthalate and other long-chain esters into corresponding 1, 2-cyclohexane dicarboxylic acid binary ester through hydrogenation. The catalyst for converting the diisononyl phthalate, the diisooctyl ph...

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Hauptverfasser: MA LIXIN, DING YUNJIE, LIN PEIZI, DIAO CHENGJI
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides a catalyst for converting diisononyl phthalate, diisooctyl phthalate, dibutyl phthalate and other long-chain esters into corresponding 1, 2-cyclohexane dicarboxylic acid binary ester through hydrogenation. The catalyst for converting the diisononyl phthalate, the diisooctyl phthalate, the dibutyl phthalate and other long-chain esters into corresponding the 1,2-cyclohexane dicarboxylic acid binary ester through the hydrogenation consists of main active ingredients, additives and carriers, wherein the main active ingredients are noble metal Ru and Pd; the additives are Fe, Co, Ni, Cu and other metals or oxides; and macroporous Al2O3, ZrO2, TiO2 and the like are selected as the carriers. Under certain temperature, certain hydrogen pressure and the action of the catalyst, the diisononyl phthalate, the diisooctyl phthalate, the dibutyl phthalate and other long-chain esters in a trickle bed reactor can be converted into the corresponding the 1, 2-cyclohexane dicarboxylic acid binary ester wit