Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide

A cyclic ketone/alcohol mixture is prepared by catalytic oxidation of the corresponding cycloalkane or catalytic decomposition of the corresponding cycloalkyl hydroperoxide. Gold supported on a porous crystalline silicate containing less than about 2 wt. % aluminum or a crystalline phosphate is used...

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1. Verfasser: PIRUTKO LANSA V.,KHARITONOV ALEXANDER S.,KHRAMOV MIKHAIL L.,URIARTE ANTHONY K
Format: Patent
Sprache:eng
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Zusammenfassung:A cyclic ketone/alcohol mixture is prepared by catalytic oxidation of the corresponding cycloalkane or catalytic decomposition of the corresponding cycloalkyl hydroperoxide. Gold supported on a porous crystalline silicate containing less than about 2 wt. % aluminum or a crystalline phosphate is used as a catalyst. The support material optionally contains one or more heteroatoms.