Polyethylene resins with bimodal molecular weight distribution and use

Bimetallic catalyst for producing polyethylene resins with a bimodal molecular weight distribution, its preparation and use. The catalyst is obtainable by a process which includes contacting a support material with an organomagnesium component and carbonyl-containing component. The support material...

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1. Verfasser: BARRY DAVID BRUCE,DIAMOND GARY M.,FRUITWALA HITESH A.,MINK ROBERT IVAN,NOWLIN THOMAS EDWARD,ONG SHIH-MAY CHRISTINE,SHIRODKAR PRADEEP P.,WANG CHUNMING
Format: Patent
Sprache:eng
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Zusammenfassung:Bimetallic catalyst for producing polyethylene resins with a bimodal molecular weight distribution, its preparation and use. The catalyst is obtainable by a process which includes contacting a support material with an organomagnesium component and carbonyl-containing component. The support material so treated is contacted with a non-metallocene transition metal component to obtain a catalyst intermediate, the latter being contacted with an aluminoxane component and a metallocene component, This catalyst may be further activated with, e.g., alkylaluminum cocatalyst, and contacted, under polymerization conditions, with ethylene and optionally one or more comonomers, to produce ethylene homo- or copolymers with a bimodal molecular weight distribution and improved resin swell properties in a single reactor. These ethylene polymers are particularly suitable for blow molding applications.