Oxydehydrogenation catalyst, and process for the catalytic conversion of isobutyric acid or functional derivatives thereof into corresponding alpha, beta-unsaturated compounds

Isobutyric acid or functional derivatives thereof, for example lower alkyl esters, are oxidatively dehydrogenated in order to achieve vapour-phase conversion thereof into the corresponding alpha , beta -ethylenically unsaturated derivative by contact with a heterogeneous catalyst in the presence of...

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Bibliographische Detailangaben
Hauptverfasser: DANIEL, CHELLIAH, BRUSKY, PHYLLIS L
Format: Patent
Sprache:eng ; ger
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Zusammenfassung:Isobutyric acid or functional derivatives thereof, for example lower alkyl esters, are oxidatively dehydrogenated in order to achieve vapour-phase conversion thereof into the corresponding alpha , beta -ethylenically unsaturated derivative by contact with a heterogeneous catalyst in the presence of molecular oxygen. The catalyst comprises calcined phosphates of iron which contain silver, cobalt, lanthanum or tellurium as modifying or doping component.