2,2'-AZOIMIDAZOLDERIVATE, VERFAHREN FUER IHRE HERSTELLUNG, FLUESSIGKRISTALLINES MATERIAL UND EINE ELEKTROOPTISCHE VORRICHTUNG

PCT No. PCT/SU81/00059 Sec. 371 Date Mar. 23, 1982 Sec. 102(e) Date Mar. 23, 1982 PCT Filed Jun. 25, 1981 PCT Pub. No. WO82/00472 PCT Pub. Date Feb. 18, 1982.2,2-azimidazole derivatives of the formula: I II wherein R and R1 are H, a C1-C12 alkyl, a C1-C12 alkoxy; NO2; R2 is hydrogen, a C1-C3 alkyl;...

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Hauptverfasser: BLINOV, LEV MIKHAILOVICH, SEVOSTYANOV, VLADIMIR PETROVICH, TITOV, VIKTOR VASILIEVICH, RUMYANTSEV, VLADIMIR GRIGORIEVICH, LAZAREVA, VALENTINA TIMOFEEVNA, NEFEDOV, VIKTOR ANDREEVICH, PRUDNIKOVA, ELENA KARLOVNA, SHOSHIN, VADIM MIKHAILOVICH, PLJUSNINA, TAMARA SERGEEVNA, IVASCHENKO, ALEXANDR VASILIEVICH
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Zusammenfassung:PCT No. PCT/SU81/00059 Sec. 371 Date Mar. 23, 1982 Sec. 102(e) Date Mar. 23, 1982 PCT Filed Jun. 25, 1981 PCT Pub. No. WO82/00472 PCT Pub. Date Feb. 18, 1982.2,2-azimidazole derivatives of the formula: I II wherein R and R1 are H, a C1-C12 alkyl, a C1-C12 alkoxy; NO2; R2 is hydrogen, a C1-C3 alkyl; n, m=1 to 3, but where n-m=1, R=R1=R2=H is excluded, are disclosed as well as a method for preparing these compounds by oxidation of a compound of the formula III wherein R, R1, R2, n and m are as identified above, except for the compound, wherein R=R2=R2=H, n=m=1. A liquid-crystal or mesomorphic material containing the 2,2'-azoimidazole compounds and electrooptical device comprised of such mesomorphic material are disclosed. The electrooptical devices are useful for systems of electronic representation and processing of information. The compounds therein have two spectrally spaced absorption bands in the visible part of their spectrum such that their position insures the contrast required for the human eye to be able to readily recognize the difference in color.