Process for the preparation of polydodecanamide, and copolymers based thereon

The proposed process for the preparation of polydodecanamide or copolymers based thereon proposes melting omega -dodecalactam or a mixture thereof with amido-forming monomers and polymerising the resultant melt at a temperature of 180-320 DEG C in the presence of a catalyst and in the presence of a...

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Hauptverfasser: MARIA GEORGIEVNA PLATOSHKINA, VLADIMIR ALEXANDROVICH EVSEEV, BORIS PAVLOVICH CHEBURASHKO, VLADIMIR PETROVICH NEFEDOV, EVGENY SOLOMONOVICH ARTSIS, MARINA KONSTANTINOVNA DOBROKHOTOVA, LJUDMILA IVANOVNA VALYSHKINA, GENNADY ABOVICH ENENSHTEIN
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creator MARIA GEORGIEVNA PLATOSHKINA
VLADIMIR ALEXANDROVICH EVSEEV
BORIS PAVLOVICH CHEBURASHKO
VLADIMIR PETROVICH NEFEDOV
EVGENY SOLOMONOVICH ARTSIS
MARINA KONSTANTINOVNA DOBROKHOTOVA
LJUDMILA IVANOVNA VALYSHKINA
GENNADY ABOVICH ENENSHTEIN
description The proposed process for the preparation of polydodecanamide or copolymers based thereon proposes melting omega -dodecalactam or a mixture thereof with amido-forming monomers and polymerising the resultant melt at a temperature of 180-320 DEG C in the presence of a catalyst and in the presence of a molecular weight regulator. According to the invention, the polymerisation is preceded by filtration of the resultant melt through a layer which contains first oxidised particles of omega -dodecalactam with an elemental oxygen content of 10-24% by weight.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Process for the preparation of polydodecanamide, and copolymers based thereon
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