Procédé pour la préparation de cétones insaturées

1,240,310. Cycloolefinic unsaturated alcohols. R. FIRMENICH, G. FlRMENICH, R. E. FIRMENICH and F. H. FIRMENICH, [trading as FIRMENICH & CIE.]. 7 Nov., 1968 [9 Nov., 1967; 1 Nov., 1968], No. 3392/71. Divided out of 1,240,309. Heading C2C. The invention comprises compounds of the general formulµ i...

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Hauptverfasser: OHLOFF,GUENTHER,DR, STOLL,MAX,DR, KOVATS,ERWIN,DR, DEMOLE,EDOUARD,DR
Format: Patent
Sprache:fre
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Zusammenfassung:1,240,310. Cycloolefinic unsaturated alcohols. R. FIRMENICH, G. FlRMENICH, R. E. FIRMENICH and F. H. FIRMENICH, [trading as FIRMENICH & CIE.]. 7 Nov., 1968 [9 Nov., 1967; 1 Nov., 1968], No. 3392/71. Divided out of 1,240,309. Heading C2C. The invention comprises compounds of the general formulµ in which the dotted lines represent a double bond in either the 1- or 2-position in the ring. They may be prepared by reacting α- or (#-cyclocitral with an organometallic compound of formula ME-CH=CH-CH 3 or ME-C=C-CH 3 , in which ME is a metal function, e.g. Li- or BrMg-, and hydrolysing the product.