SOL GEL FUNCTIONALIZED SILICATE CATALYST AND SCAVENGER

SOL GEL FUNCTIONALIZED SILICATE CATALYST AND SCAVENGER

This invention relates to materials suitable as metal scavengers and catalysts. The materials are prepared by functionalizing silicate materials such as silica or SBA-15 with a thiol or amine, or other functionalizing agent, in a sol gel process. In a preferred embodiment, the metal is palladium and...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: BLANC, ALEXANDRE, SATEESH, MUTYALA, CRUDDEN, CATHLEEN M
Format: Patent
Sprache:eng ; fre
Schlagworte:
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS THEREOF
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
THEIR RELEVANT APPARATUS
TRANSPORTING
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Beschreibung
Zusammenfassung:This invention relates to materials suitable as metal scavengers and catalysts. The materials are prepared by functionalizing silicate materials such as silica or SBA-15 with a thiol or amine, or other functionalizing agent, in a sol gel process. In a preferred embodiment, the metal is palladium and the functionalizing agent is a thiol. The material may be used as a catalyst for the Suzuki-Miyaura and Mizoroki-Heck coupling reactions. The catalyst materials have extremely low metal leaching, are very stable, and are completely recyclable.