HYDROGENATION OF AROMATIC AMINES TO ALICYCLIC AMINES USING A LITHIUM ALUMINATE-BASED CATALYST

The present invention relates to processes for the catalytic hydrogenation of aromatic amines to their acyclic counterparts using a ruthenium catalyst on a lithium aluminate support. The hydrogenation process comprises contacting an aromatic amine with hydrogen in the presence of a ruthenium catalys...

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Bibliographische Detailangaben
Hauptverfasser: EMIG, LENORE ANN, LUTZ, EUGENE GEORGE, DING, HAO, VEDAGE, GAMINI ANANDA, ENGEL, MATTHEW J
Format: Patent
Sprache:eng ; fre
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Beschreibung
Zusammenfassung:The present invention relates to processes for the catalytic hydrogenation of aromatic amines to their acyclic counterparts using a ruthenium catalyst on a lithium aluminate support. The hydrogenation process comprises contacting an aromatic amine with hydrogen in the presence of a ruthenium catalyst under temperature and pressure conditions suitable to effect ring hydrogenation. The process is especially useful for hydrogenating aniline to cyclohexylamine.