PROCESS FOR PREPARING ALPHA-HYDROXY CARBOXYLIC ACIDS AND ESTERS THEREOF

The invention relates to a process for the selective, economically viable preparation of methacrylic acid and methacrylic esters starting from acetone cyanohydrin, wherein, in a first step, 2-hydroxy-2-methylpropionic acid is prepared by reacting acetone cyanohydrin with sulphuric acid in the presen...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: SCHULTHEIS, FRIEDEL, GROEMPING, MATTHIAS, GROPP, UDO, KRILL, STEFFEN
Format: Patent
Sprache:eng ; fre
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Zusammenfassung:The invention relates to a process for the selective, economically viable preparation of methacrylic acid and methacrylic esters starting from acetone cyanohydrin, wherein, in a first step, 2-hydroxy-2-methylpropionic acid is prepared by reacting acetone cyanohydrin with sulphuric acid in the presence of water and a suitable polar solvent and is isolated and methacrylic acid is subsequently prepared by .beta.-elimination of water starting from 2-hydroxy-2-methylpropionic acid.