PROCESS FOR PRODUCTION OF 1-ARYL-5-(TRIFLUOROMETHYL)-1H-TETRAZOLES

PROCESS FOR PRODUCTION OF 1-ARYL-5-(TRIFLUOROMETHYL)-1H-TETRAZOLES

A process for the production of N-aryl-2,2,2-trifluoro- acetimidoyl chloride represented by the general formula (2) by reacting a 2,2,2-trifluoro-N- arylacetamide represented by the general formula (1) with both at least one member selected from the group consisting of phosphorus oxychloride and dip...

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Bibliographische Detailangaben
Hauptverfasser: MITSUI, SUNAO, SATO, YASUHIRO, KOGURO, KIYOTO, HAGIYA, KAZUTAKE
Format: Patent
Sprache:eng ; fre
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
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Zusammenfassung:A process for the production of N-aryl-2,2,2-trifluoro- acetimidoyl chloride represented by the general formula (2) by reacting a 2,2,2-trifluoro-N- arylacetamide represented by the general formula (1) with both at least one member selected from the group consisting of phosphorus oxychloride and diphenyl- phosphoric acid chloride and a tertiary amine in an organic solven t; and a process for the production of 1-aryl-5 -(trifluoromethyl)-1H-tetrazole s represented by the general formula (4) by reacting an N-aryl-2,2,2- trifluoroacetimidoyl chloride represented by the general formula (2) with an azide in an aromatic hydrocarbon solvent in the presence of an amine salt.