A PROCESS FOR THE MANUFACTURE OF DIETHYLENETRIAMINE AND HIGHER POLYETHYLENEPOLYAMINES

A PROCESS FOR THE MANUFACTURE OF DIETHYLENETRIAMINE AND HIGHER POLYETHYLENEPOLYAMINES

The invention relates to a process for the manufacture of diethylenetriamine and higher polyethylenepolyamines by a transamination of ethylenediamine. The transamination is performed at a temperature from 135~C to 180~C at a pressure from 5 Mpa to 40 Mpa in the presence of hydrogen and a particulate...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: EKENBERG, KRISTINA, LIF, JOHAN
Format: Patent
Sprache:eng ; fre
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The invention relates to a process for the manufacture of diethylenetriamine and higher polyethylenepolyamines by a transamination of ethylenediamine. The transamination is performed at a temperature from 135~C to 180~C at a pressure from 5 Mpa to 40 Mpa in the presence of hydrogen and a particulate catalysts containing 26 to 65% by weight of nickel on an oxide carrier. A high conversion degree of ethylenediamine and a high selectivity to form acyclic polyethylenepolyamines, such as diethylenetriamine are obtained by the process. The formation of cyclic amine compounds, e.g. piperazine, is low.