HYDROCARBON SYNTHESIS WITH CRYOGENIC NITROGEN REMOVAL UPSTREAM OF THE SYNGAS GENERATION

In a hydrocarbon synthesis process, nitrogen is cryogenically removed from natural gas to produce a synthesis gas feed comprising methane which is substantially free of nitrogen. This feed is converted to a synthesis gas comprising a mixture of H2 and CO which is substantially free of the HCN and NH...

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Bibliographische Detailangaben
Hauptverfasser:	COULALOGLOU, CONSTANTINE A, ALEXION, DENNIS G
Format:	Patent
Sprache:	eng ; fre
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS BLASTING CHEMISTRY COMBINED HEATING AND REFRIGERATION SYSTEMS HEAT PUMP SYSTEMS HEATING LIGHTING LIQUEFACTION SOLIDIFICATION OF GASES LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS MANUFACTURE OR STORAGE OF ICE MECHANICAL ENGINEERING METALLURGY MIXTURES BY PRESSURE AND COLD TREATMENT ORGANIC CHEMISTRY REFRIGERATION OR COOLING WEAPONS
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Beschreibung
Zusammenfassung:	In a hydrocarbon synthesis process, nitrogen is cryogenically removed from natural gas to produce a synthesis gas feed comprising methane which is substantially free of nitrogen. This feed is converted to a synthesis gas comprising a mixture of H2 and CO which is substantially free of the HCN and NH3 hydrocarbon synthesis catalyst deactivating nitrogen species. This reduces the need for rejuvenating the hydrocarbon synthesis catalyst. During the cryogenic separation, C2+ hydrocarbons are separated from the natural gas and all or a portion of the separated C2-C4 hydrocarbons are added to the methane feed before it is converted into syngas, to increase syngas production. All or a portion of the separated C2-C3 hydrocarbons may be removed as LP G.