PRODUCTION OF BENZENE, TOLUENE AND XYLENE (BTX) FROM FCC NAPHTHA

Cracked naphtha feeds such as FCC naphtha and coker naphtha are upgraded to produce chemical grade BTX (benzene, toluene, xylene with ethylbenzene) while co-poducing a low sulfur gasoline of relatively high octane number. The cracked, sulfur-containing naphtha is processed by hydrodesulfurization fo...

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Hauptverfasser:	TIMKEN, HYE KYUNG CHO, ANGEVINE, PHILIP JAY
Format:	Patent
Sprache:	eng ; fre
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS CRACKING HYDROCARBON OILS FUELS GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS LUBRICANTS METALLURGY MINERAL WAXES ORGANIC CHEMISTRY PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	Cracked naphtha feeds such as FCC naphtha and coker naphtha are upgraded to produce chemical grade BTX (benzene, toluene, xylene with ethylbenzene) while co-poducing a low sulfur gasoline of relatively high octane number. The cracked, sulfur-containing naphtha is processed by hydrodesulfurization followed by treatment over an acidic catalyst, preferably a zeolite such as ZSM-5 or zeolite beta with a hydrogenation component, preferably molybdenum. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product to permit a low sulfur gasoline of blending quality to be obtained with the BTX. The BTX can be extracted from the second stage effluent, preferably from a C6 - C8 fraction of this effluent.