A Gas Phase Polymerization Employing Unsupported Catalysts

A process for the gas-phase polymerization of polymers which allows for the introduction of an unsupported polymerization catalyst system into the gas-phase reactor, wherein the unsupported polymerization catalyst system comprises (i) a non-volatile materials fraction containing a polymerization cat...

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Hauptverfasser: SMALE, MARK WILTON, WILLIAMS, CLARK CURTIS, RAMAMURTHY, ARAKALUD VENKATAPATHIA, WENZEL, TIMOTHY TODD, CARMICHAEL, KEITH ERNEST, CROPLEY, JEAN BOWMAN, KELLER, GEORGE ERNEST, LARSEN, ELDON RONALD
Format: Patent
Sprache:eng ; fre
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Zusammenfassung:A process for the gas-phase polymerization of polymers which allows for the introduction of an unsupported polymerization catalyst system into the gas-phase reactor, wherein the unsupported polymerization catalyst system comprises (i) a non-volatile materials fraction containing a polymerization catalyst; (ii) a solvent fraction which is at least partially miscible with the non-volatile materials fraction and which is sufficiently volatile to allow for the formation of polymerization catalyst particles when the mixture of the solvent fraction and the non-volatile materials fraction is sprayed into the reactor; (iii) a compressed fluid; and (iv) optionally a slowly vaporizing solvent.