ISOCYANATE COMPOSITIONS AND CELLULOSE PRODUCTS IMPREGNATED WITH THE COMPOSITIONS

The invention is directed to a composition of matter useful as a paper impregnant, to the method of its use, and to the products produced by the method. Poly (diphenylmethane diisocyanate) or PMDI has been used in the past as a paper impregnant with or without propylene carbonate as a diluent. These...

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Bibliographische Detailangaben
Hauptverfasser:	PARK, DAVID W, HUNTER, FRANK R
Format:	Patent
Sprache:	eng ; fre
Schlagworte:	ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR CHEMISTRY COMPOSITIONS BASED THEREON CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS,e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES,DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS CONVEYING HANDLING THIN OR FILAMENTARY MATERIAL IMPREGNATING OR COATING OF PAPER MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PACKAGES PACKAGING ELEMENTS PACKING PAPER NOT OTHERWISE PROVIDED FOR PAPER-MAKING PERFORMING OPERATIONS PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D PRODUCTION OF CELLULOSE PULP COMPOSITIONS STORING TEXTILES THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
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Beschreibung
Zusammenfassung:	The invention is directed to a composition of matter useful as a paper impregnant, to the method of its use, and to the products produced by the method. Poly (diphenylmethane diisocyanate) or PMDI has been used in the past as a paper impregnant with or without propylene carbonate as a diluent. These products have generally required pressing under high pressures and at elevated temperatures. It has now been found that triacetin and/or triethyl citrate in usages up to about 20% of PM DI give superior performance in impregnated products. The modified PMDI will cure at essentially ambient conditions in times as short as 1-2 days to insoluble polyureas with low residual amounts of isocyanates and reaction byproducts such as 4,4'- diaminodiphenylmethane. The treated papers can be used in applications of which skins for sandwich panels and high strength corrugated board would be exemplary.