BIFUNCTIONAL AIRELECTRODE

A bifunctional airelectrode for use in electrochemical energy cells discharges a satisfactory current on the first discharge cycle and operates for a relatively large number of charge-discharge cycles without gas forming between the electrolyte side of the air electrode and the electrolyte. The acti...

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Hauptverfasser: SMALLEY, YARDLYNE G, SHEPARD, VANCE ROGER, JR, BENTZ, RICHARD DENNIS
Format: Patent
Sprache:eng ; fre
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Zusammenfassung:A bifunctional airelectrode for use in electrochemical energy cells discharges a satisfactory current on the first discharge cycle and operates for a relatively large number of charge-discharge cycles without gas forming between the electrolyte side of the air electrode and the electrolyte. The active layer of the electrode includes an oxygen reduction catalyst having a first oxygen evolution potential and an oxygen evolution catalyst having a second oxygen evolution potential less than the first oxygen evolution potential, the oxygen reduction catalyst being present in a greater concentration proximate the electrolyte side than proximate the air side and the oxygen evolution catalyst being present in a greater concentration proximate the air side than proximate the electrolyte side.