PROCESS FOR PREPARING TRANSITION METAL CYCLOPENTADIENYL CARBONYL COMPOUNDS

Transition metal cyclopentadienyl carbonyl compounds of the formula: ¢R m C p M(CO)y!n wherein R is hydrocarbyl, C p is cyclopentadienyl, M is a transition metal, x is 0 or an integer from 1 to 5, y is an integer from 1 to 7, provided that when x is 2 to 5, R can represent two or more different hydr...

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Bibliographische Detailangaben
Hauptverfasser:	BELL, DONALD ROBERT, BERRIS, BRUCE C
Format:	Patent
Sprache:	eng ; fre
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL BLASTING CHEMISTRY COMBUSTION ENGINES COMBUSTION ENGINES IN GENERAL FIRELIGHTERS FUELS FUELS NOT OTHERWISE PROVIDED FOR HEATING HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS INTERNAL-COMBUSTION PISTON ENGINES LIGHTING LIQUEFIED PETROLEUM GAS LUBRICANTS MECHANICAL ENGINEERING METALLURGY NATURAL GAS ORGANIC CHEMISTRY PEAT PETROLEUM, GAS OR COKE INDUSTRIES SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K TECHNICAL GASES CONTAINING CARBON MONOXIDE WEAPONS
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Beschreibung
Zusammenfassung:	Transition metal cyclopentadienyl carbonyl compounds of the formula: ¢R m C p M(CO)y!n wherein R is hydrocarbyl, C p is cyclopentadienyl, M is a transition metal, x is 0 or an integer from 1 to 5, y is an integer from 1 to 7, provided that when x is 2 to 5, R can represent two or more different hydrocarbyl groups and any two R groups can together form a fused ring with the cyclopentadienyl moiety, and n is 1 or 2, are prepared in one step by carbonylating a mixture of (i) a transition metal salt of an organic carboxylic acid a .beta.-diketone, or a .beta.-keto ester (ii) a cyclopentadiene compound (iii) and a metal alkyl reducing agent.