PROCESS OF PREPARATION OF NEW CATALYSTS CONTAINING RHODIUM AND THEIR APPLICATION

The present invention refers to the compounds (.mu.-hydrazine-N1:N2)-bis¢bis(triphenylphosphine)-chlororhodium (I)! and di(.mu.-hydrazine-N1:N2)-bis¢bis(triphenylphosphine)rhodium (I)! dichloride, which are homogenous hydrogenation catalysts and their application in the hydrogenation of the exocycli...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	VILLAX, IVAN, HEGGIE, WILLIAM, SOMERVILLE, RICHARD GERARD, PAGE, PHILIP RONALD, HURSTHOUSE, MICHAEL BARRY
Format:	Patent
Sprache:	eng ; fre
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The present invention refers to the compounds (.mu.-hydrazine-N1:N2)-bis¢bis(triphenylphosphine)-chlororhodium (I)! and di(.mu.-hydrazine-N1:N2)-bis¢bis(triphenylphosphine)rhodium (I)! dichloride, which are homogenous hydrogenation catalysts and their application in the hydrogenation of the exocyclic methylene group of acid addition salts of 6-demethyl-6-deoxy-6-methylene-5-hydroxytetracycline (methacycline) to prepare .alpha.-6-deoxy-5-hydroxytetracycline (doxycycline).